Product ID:CPE 710500 SUN BROMINATING SPA TABLETS
MSDS Date:06/05/1989
FSC:6850
NIIN:00F013989
MSDS Number: BJTKF

OLIN CORPORATION

120 LONG RIDGE ROAD
STAMFORD, CT 06904

Emergency Phone: (800) 654-6911

Info Phone: (800) 654-6911

Cage: 0G578

OLIN CORPORATION

STAMFORD, CT 06904-1355 US

Telephone: 203-356-3449

Cage: 0G578

1-BROMO-3-CHLORO-5, 5 DIMETHYLHYDANTOIN

CAS: 16079-88-2

RTECS: MI9195400

Fraction By Weight: 60-65%

OSHA PEL NONE

ACGIH TLV: NONE

1,3-DICHLORO-5,5-DIMETHYL HYDANTOIN

CAS: 118-52-5

RTECS: MU0700000

Fraction By Weight: 25-30%

OSHA PEL 0.2MG/M3/0.4STEL

ACGIH TLV: 0.2 MG/M3/0.4STEL;93

1,3-DICHLORO-5-ETHYL-5-METHYLHYDANTOIN

CAS: 89415-87-2

Fraction By Weight: 10-15%

SODIUM CHLORIDE

CAS: 7647-14-5

RTECS: VZ4725000

Fraction By Weight: 1-5%

LD50 LC50 Mixture:ORAL RATS LD50 = 542-760 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MUCUS MEMBRANE/LUNG
IRRITATION, COUGHING & CHOKING. SKIN: IRRITATION, CORROSIVE,
DESTRUCTION OF TISSUE, ALLERGIC REACTION/SENSITIZATION. EYE:
CORROSIVE, BURNS W/PERMANENT DAMAGE & IMPAIRME NT OF VISION.
INGESTION: BURNS OF THE MOUTH/THROAT, GASTROENTERITIS, NAUSEA,
VOMITING, LETHARGY, DIARRHEA/ULCERATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:ANIMAL STUDIES HAVE BEEN PERFORMED ON EACH OF
THE HYDANTOIN DERIVATIVES. SKIN: REPEATED CONTACT CAUSE ALLERGIC
REACTIONS.
Medical Cond Aggravated by Exposure:ASTHMA & OTHER RESPIRATORY DISEASES

First Aid:EYES/SKIN: FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. INGESTION: DRINK LARGE QUANTITIES OF WATER. DON'T INDUCE
VOMITING. DON'T GIVE ANYTHING BY MOUTH IF THE PERSON IS UNCONSCIOUS
OR IF HA VING CONVULSIONS. INHALATION: MOVE TO FRESH AIR. IF
BREATHING IS DIFFICULT, ADMINISTER OXYGEN. KEEP PERSON WARM & REST.
IF BREATHING HAS STOPPED, ARTIFICIAL RESPIRATION SHOULD BE GIVEN
IMMEDIATELY.

Extinguishing Media:USE WATER SPRAY OR FOG, HEAVY DELUGE OR FOG STREAMS
Fire Fighting Procedures:USE WATER TO COOL CONTAINERS EXPOSED TO FIRE.
IF MATERIAL IN INVOLVED IN FIRE, HAZARDOUS CONCENTRATIONS OF GASES
MAY BE FORMED.

Spill Release Procedures:HAZARDOUS CONCENTRATIONS IN AIR MAY BE FOUND
IN LOCAL SPILL AREA. STOP SOURCE OF SPILL IF SAFE TO DO SO. DON'T
PLACE SPILLED MATERIAL IN TO ITS ORIGINAL CONTAINER. PUT SPILL
MATERIALS INTO A PLASTIC B AG IN A CLEAN, DRY CONTAINER APPROVED
FOR MATERIAL

Handling and Storage Precautions:CARE MUST BE TAKEN TO PREVENT
ENVIRONMENTAL CONTAMINATION FROM THE USE OF THIS MATERIAL. DON'T
TAKE INTERNALLY. AVOID CONTACT W/SKIN, EYE & CLOTHING.
Other Precautions:STORE IN A CLEAN, DRY, WELL VENTILATED AREA. AVOID
EXCESS HEAT, DIRECT SUNLIGHT & HIGH HUMIDITY OR MOISTURE. DON'T
STORE AT TEMPS >90F. IF DAMP OR WET MIX W/CLEAN SAND TO STABILIZE
&/OR DESTROY MATERI AL. THIS MATERIAL IS HEAVIER THAN WATER.

Respiratory Protection:RESPIRATORY PROTECTION NOT NORMALLY NEEDED. IF
DUSTING EXISTS, WEAR NIOSH/MSHA APPROVED DUST RESPIRATOR.
Ventilation:LOCAL EXHAUST/MECHANICAL: RECOMMENDED
Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL GOGGLES
Other Protective Equipment:BOOTS, HARD HAT, IMPERVIOUS CLOTHING,
CHEMICALLY IMPERMEABLE SUIT.
Work Hygienic Practices:IN CALL CASES, ENSURE ADEQUATE VENTILATION &
PROVIDE RESPIRATORY PROTECTION BEFORE THE PERSON RETURNS TO WORK.
Supplemental Safety and Health
THIS PRODUCT IS REGULATED UNDER THE FEDERAL INSECTICIDE, FUNGICIDE &
RODENTICIDE ACT. THE ONLY REGISTERED USE IS IN AN ALGAECIDE. A
COMPONENT OF THIS PRODUCT ISN'T LISTED ON THE TOXIC SUBSTANCE
CONTRO L ACT INVENTORY.

Melt/Freeze Pt:M.P/F.P Text:248-298F
Decomp Temp:Decomp Text:329F
pH:3.6
Solubility in Water:0.54%
Appearance and Odor:WHITE TO OFF-WHITE GRANULES OR TABLETS/BRIQUETTES;
SLIGHT, PUNGENT ODOR.
Percent Volatiles by Volume:<0.5%

Stability Indicator/Materials to Avoid:YES
PAPER, CARDBOARD, OXIDIZERS, STRONG ACIDS/BASES, REDUCING AGENTS,
HYDRATED SALTS, ORGANIC/NITROGEN CONTAINING COMPOUNDS
Stability Condition to Avoid:HEAT, DIRECT SUNLIGHT, HIGH HUMIDITY OR
MOISTURE. DON'T TEMPS >790F.
Hazardous Decomposition Products:CO, HYDROGEN BROMIDE/CHLORIDE,
CYANATES, & OTHER UNIDENTIFIED NOXIOUS GASES

Waste Disposal Methods:THIS MATERIAL MAY BE NEUTRALIZED FOR DISPOSAL.
AS A HAZARDOUS SOLID WASTE, IT MUST BE DISPOSED OF IN ACCORDANCE
W/LOCAL, STATE, & FEDERAL REGULATIONS IN A PERMITTED HAZARDOUS
WASTE TREATMENT, STORAGE & DISPOSAL FACILITY BY TREATMENT. EPA
WASTE: D001.

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disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.